SINOMER® SMA
Long-Chain Methacrylate Monomer for High-Hydrophobicity and Polymer Modification
Chemical Name: Stearyl methacrylate;Octadecyl methacrylate
CAS No.: 32360-05-7
MF: C22H42O2 MW: 338.57
Molecular structure:

SINOMER® SMA (Stearyl Methacrylate) is a long-chain hydrophobic methacrylate monomer featuring a C18 alkyl group and a polymerizable methacrylate double bond. Compared to its acrylate counterpart (SA), the α-methyl group in SMA provides higher glass transition temperature (Tg) and better thermal stability in homopolymers, while maintaining excellent flexibility and low shrinkage. Its long hydrophobic side chain offers outstanding water resistance, weather resistance, and compatibility with non-polar systems.
| Item | Specification |
| Appearance | White solid to liquid |
| Assay | ≥96% |
| Acid Value | ≤0.5 mg KOH/g |
| Inhibitor (MEHQ), ppm | ≤500 |
Low curing shrinkage and low volatility
Excellent flexibility and toughness
Higher Tg compared to stearyl acrylate for better heat resistance
Outstanding weather resistance and water resistance
Long C18 hydrophobic chain for effective hydrophobicity
Good compatibility with oil-based and non-polar systems
SINOMER® SMA is a versatile hydrophobic monomer used in a wide range of polymer synthesis applications:
Coatings & Inks – Used as a hydrophobic comonomer in coatings, printing inks, and release coatings, where it improves water resistance, flexibility, and weatherability.
Textile & Leather Auxiliaries – Applied in textile dyeing and finishing auxiliaries, leather auxiliaries, and waterproof/oil-proofing agents, providing durable hydrophobic protection.
Lubricating Oil Additives – Used in the synthesis of lubricating oil additives and flow improvers, where the long alkyl chain effectively modifies viscosity-temperature behavior.
Crude Oil Viscosity Reducers – Functions as a monomer for polymeric flow improvers and pour point depressants in crude oil transportation.
Adhesives & Sealants – Improves flexibility, moisture resistance, and adhesion in various adhesive formulations.
● 150kgs/drum.
Being kept in dry, clean warehouse with well ventilation.
Avoid exposing to light and heating.
Protecting the product from leakage, rain and insolation during transportation.
We offer a variety of options to help you find the right product for your application
Provide formulation optimization support for water-based/solvent-based systems
Full coverage of REACH, FDA, and GB standards
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