SINOMER PM839 - Polythiol Curing Agent Alternative to Toray QE-340M

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SINOMER® PM839: Alternative to Toray QE-340M (Curing Properties Comparison)

SINOMER® PM839: The High-Performance, Cost-Effective Alternative to Toray QE-340M

For formulators and engineers seeking reliable, fast-curing epoxy systems — particularly under challenging low-temperature conditions — the choice of curing agent is critical. Toray POLYTHIOL QE-340M has long been a recognized option in this field. Today, we present SINOMER® PM839: a technically comparable, domestically produced, and cost-competitive alternative that matches or exceeds key performance benchmarks, offering a reliable solution for your supply chain.

This direct comparison demonstrates how SINOMER® PM839 serves as a drop-in replacement for QE-340M, with the added benefits of transparent data, accessible support, and enhanced value.

Curing Properties of SINOMER® PM839

Curing Performance Data

Test Formulation: E51/BER-128 : PM839 : DMP-30 = 100 g : 100 g : 10 g

Property

Condition

Result

Gel Time

–5°C

3 min 20 s


27°C, 70% RH

2 min 40 s

Hardness (Shore D), 24h

–5°C

75


27°C, 70% RH

84

Lap Shear Strength (MPa), 24h

–5°C

9


27°C, 70% RH

19

  • Notes:

  • Hardness sample size: φ35 mm × 6 mm

  • Lap shear substrate: steel, 25 mm × 100 mm × 1.6 mm




 

Hardness Development Over Time

SINOMER® PM839 cures rapidly even at low temperatures and develops high hardness. Data shown for –5°C and 27°C / 70% RH.

 

Formulation A:  E51/BER-128 : PM839 : DMP-30 = 100 : 100 : 5

Formulation B:  E51/BER-128 : PM839 : DMP-30 = 100 : 100 : 10

Time

Formulation A

Formulation B


–5°C

27°C, 70% RH

–5°C

27°C, 70% RH

0.5 h

66

73

68

78

1 h

67

75

70

82

3 h

65

76

75

82

24 h

70

78

75

84

3 d

68

79

74

82

  • *Note: 

  • DMP-30 is 2,4,6-Tris(dimethylaminomethyl)phenol.

  • Hardness sample size: φ35 mm × 6 mm.*

 

 

Figure 1.

Hardness development of E51(BER-128) / PM839 / DMP-30 at –5°C and  27°C / 70% RH

(Left: 100:100:5; Right: 100:100:10)



Lap Shear Strength Development Over Time

SINOMER® PM839 develops high lap shear strength quickly, even at low temperatures.

 

Formulation A:  E51/BER-128 : PM839 : DMP-30 = 100 : 100 : 5

Formulation B:  E51/BER-128 : PM839 : DMP-30 = 100 : 100 : 10

Time

Formulation A

Formulation B


–5°C

27°C, 70% RH

–5°C

27°C, 70% RH

0.5 h

4 MPa

7 MPa

6 MPa

12 MPa

1 h

5 MPa

8 MPa

9 MPa

16 MPa

3 h

6 MPa

10 MPa

7 MPa

18 MPa

24 h

11 MPa

18 MPa

9 MPa

19 MPa

3 d

12 MPa

20 MPa

9 MPa

17 MPa

Note: Substrate for lap shear: steel, 25 mm × 100 mm × 1.6 mm.

 

Figure 2.

Lap shear strength development of E51(BER-128) / PM839 / DMP-30 at –5°C and 27°C / 70% RH

(Left: 100:100:5; Right: 100:100:10)


Direct Performance Comparison: Specification & Data

The table below provides a clear, side-by-side comparison of core specifications and curing performance, based on publicly available TDS data and our internal testing.

Property / TestToray POLYTHIOL QE-340MSINOMER® PM839Key Takeaway
AppearanceClear liquidColorless transparent liquidComparable
Viscosity @ 25°C10.0–18.0 Pa·s12,000–14,000 mPa·sSimilar range
Color (APHA/Hazen)≤ 300 (Typ. 15)≤ 20Superior color
Mercaptan Content10.0–14.0 wt%12.5 wt%Directly comparable activity
Gel Time @ ~5°C7.5 min (at 5°C)~3.3 min (at -5°C)Faster cure under more severe conditions
Gel Time @ Ambient3.5 min (23°C)2.7 min (27°C)Comparable / faster
Hardness, 24h (Shore D)79 (5°C) / 84 (23°C)75 (-5°C) / 84 (27°C)Achieves same final hardness
Lap Shear Strength, 24h15 MPa (5°C & 23°C)9 MPa (-5°C) / 19 MPa (27°C)Higher strength at ambient
Low-Temp ValidationData at 5°CData at -5°CTested under harsher conditions

*Note: Gel time and strength tests for SINOMER® PM839 conducted with catalyst DMP-30. Toray data uses catalyst EHC-30. Both catalysts are tris-dimethylaminomethyl phenol derivatives, ensuring comparable acceleration mechanisms.*


Why SINOMER® PM839 is a Smart Alternative to QE-340M


1. Matched or Superior Technical Performance

  • Curing Speed: PM839 demonstrates a significantly faster gel time at lower temperatures, potentially improving production cycle times.

  • Final Properties: It achieves the same high final hardness (Shore D 84) and offers higher lap shear strength at room temperature.

  • Low-Temperature Assurance: With performance data validated at -5°C, PM839 provides extra confidence for applications in cold environments.


2. Supply Chain & Economic Advantages

  • Cost-Effectiveness: As a domestically manufactured product, SINOMER® PM839 typically offers a favorable price-to-performance ratio, reducing formulation costs without sacrificing quality.

  • Logistical Simplicity: Avoid import delays, complex logistics, and currency fluctuations. Enjoy shorter lead times and reliable supply.

  • Direct Technical Support: Access direct communication with our application engineers for formulation troubleshooting and optimization support.


3. Seamless Replacement Formulation Guidelines

For a direct substitution in formulations currently using QE-340M, we recommend the following starting point:

  • Replace QE-340M with SINOMER® PM839 on a 1:1 weight basis.

  • Use the same amine catalyst (e.g., DMP-30, EHC-30, or similar tertiary amines) at the standard recommended dosage (e.g., 5-10 phr).

  • Conduct a small-scale gel time and property verification test to fine-tune for your specific epoxy resin and process conditions.


This straightforward approach minimizes reformulation effort and accelerates your validation process.


Conclusion: A Strategic Shift to Value

Choosing SINOMER® PM839 is not just about finding an alternative; it's about making a strategic decision for equal performance, greater security, and better value. It delivers the rapid, low-temperature cure required for demanding applications in adhesives, coatings, and composites, while providing the tangible benefits of a localized, responsive supply chain.


Ready to make the switch? Contact us today to request a sample of SINOMER® PM839 and detailed technical documentation. Our team is ready to support your testing and integration process.


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